Tetrakis(N,N-diethylcarbamato)titanium(IV)
نویسندگان
چکیده
The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007